A radioactive sample loses the same fraction of its remaining atoms in every hour, and a cup of coffee in a quiet room loses roughly the same fraction of its excess over room temperature in every minute. How long until half the sample is gone, and when will the coffee be cool enough to drink? Both questions lead to a rate proportional to the quantity that is changing. This lesson solves that equation, reads off the half-life and the time constant, and applies the same idea to a temperature difference in Newton’s law of cooling.
Key terms
Proportional rate of change
Definition With as the independent variable and , a quantity has a rate of change proportional to itself if
for a constant . The constant has units of inverse time, and wherever it equals the relative rate . Every solution is defined for all and has the form
where . No solution is missed, because , so is constant on any interval where solves the equation.
In plain words The rate is a fixed multiple of the current amount. Twice as much material changes twice as fast, so the same fraction of the amount changes in every unit of time.
Example Separation gives the same formula. On an interval where , dividing by gives , so and . The zero function, lost in the division, is the case . For instance, the problem with in years and has the solution , and .
Exponential growth and decay
Definition Let with . If , the solution increases without bound, which is exponential growth. If , it decreases toward as but stays positive at every finite time, which is exponential decay. If , it is constant. In every case, for all and every time step ,
so equal time steps multiply the amount by equal factors. On the phase line of , the equilibrium is unstable for and asymptotically stable for .
In plain words Exponential change multiplies by the same factor over each equal stretch of time, while linear change adds the same amount. Because the amount changes, the absolute rate changes with it.
Example Take and per hour, so and the amount triples every hour. A linear model with the same increase in the first hour adds every hour.
| Hour | ||||
|---|---|---|---|---|
| Exponential | ||||
| Linear |
The exponential rate is about per hour when and about per hour when .
Half-life
Definition For decay write with , so and with . The half-life is the time in which the amount falls to half its value. It solves , so
The same duration halves the amount from any starting time, since for every . After half-lives the amount is , and in general . For growth with the doubling time plays the same role.
In plain words Each half-life removes half of what is left, not half of the original amount. So the amount keeps halving and never reaches zero at a finite time.
Example Start with units and a half-life of hours. Then, with in hours,
So , and . Differentiating gives , and , so the formula satisfies both the rate law and the starting amount.
Time constant
Definition For with , the time constant is , measured in units of time, so . Over each time constant the amount is divided by ,
so about percent remains and about percent is lost. The two time scales are related by , so the time constant is about half-lives. The tangent line to the decay curve at any time reaches zero exactly one time constant later. For growth with , the same name is used for , the time in which the amount grows by the factor .
In plain words The time constant is the natural clock of the decay. If the amount kept falling at its current rate, it would be gone after one time constant, but the rate shrinks along with the amount, so about percent is still there.
Example For the -hour half-life above, hours, which is longer than the half-life, and units. Measured in minutes, the same decay has per minute and minutes, the same duration. The product must have no units, so and have to use the same time unit.
Newton’s law of cooling
Definition Let be the temperature of an object at time , with , and let be the constant ambient temperature of its surroundings. Newton’s law of cooling is the model
where is a constant with units of inverse time. If the rate is negative and the object cools, and if the rate is positive and it warms. The difference satisfies , so with
The model assumes that the object has nearly the same temperature throughout, that heat flows at a rate proportional to the temperature difference, and that the surroundings stay at .
In plain words The excess of the object’s temperature over the room’s decays exponentially. A hot object cools and a cold one warms, both toward , and the time constant belongs to that excess, not to the temperature itself.
Example Put an object at in a room at , with per minute. The initial difference is , and with in minutes
so . Differentiating gives , which equals , so the formula solves the equation. After one time constant, minutes, the excess is and . The object reaches when , at minutes.
Constant ambient temperature
Definition The ambient temperature is the temperature of the surroundings. Newton’s formula assumes it is a constant , which is reasonable when the surroundings are large enough that the object does not noticeably heat or cool them. Then the equilibrium is asymptotically stable, and every solution tends to it as . If the ambient temperature changes with time, with differentiable, the difference satisfies
so the constant-ambient formula no longer solves the equation unless is zero. The equation is still linear, and the integrating factor solves it.
In plain words A fixed room temperature is the target of the motion. If the target moves, the object chases it, and the simple exponential formula no longer describes the chase.
Example A can at sits in a room at with per minute. Here , so , which rises toward . The excess is negative and shrinks in size, and the can is halfway, at , after minutes. That halfway time does not depend on the starting temperature, because every minutes halves the excess, whatever its size.
Check yourself
- A gram sample decays with a half-life of days. How much remains after days, and what is the time constant?
Show the answer
Fifteen days are half-lives, so the amount left, in grams, is
The decay rate is per day, so the time constant is days.
- Coffee at sits in a room at and has cooled to after minutes. Assuming Newton’s law of cooling, when does it reach ? A classmate models the temperature itself as . What answer does that give, and what is wrong with it?
Show the answer
The excess over the room decays, so . At the excess is , so and per minute. The temperature is when the excess is , so and
minutes. The classmate’s model gives and then , so minutes, which is too early. That model sends the temperature toward , below the room, while Newton’s law moves it toward and never past it. The quantity that decays is the difference , not .
- The room warms steadily, with in degrees Celsius and in minutes, and an object starts at with per minute. Show that is not a solution, then solve the problem and describe the long-run behavior.
Show the answer
For that guess, while , so the two sides differ by . The equation is linear,
Multiplying by gives . Integration by parts gives the antiderivative , so , and gives . The solution is
Since , the object ends up trailing the room by . The lag is , the warming rate times the time constant.